(2S,4'R,5'R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
The title compound, C27H30O6, was prepared by monodihydroxylation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenylpent-4-enoate using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1'-carbonyl diimidazole. In the crystal structure, the phenyl rings form an intramolecular edge-to-face C-H contact with an interplanar angle of 56.4° and a Hcentroid distance of 3.03 Å.
Originalsprog | Engelsk |
---|---|
Tidsskrift | Acta Crystallographica. Section E: Structure Reports Online |
Vol/bind | 64 |
Udgave nummer | 2 |
Sider (fra-til) | 530 |
ISSN | 1600-5368 |
DOI | |
Status | Udgivet - 1 feb. 2008 |
Eksternt udgivet | Ja |
ID: 49636020