(1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate
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The title compound, C28H24N2O5, was prepared from (E)-2-cinnamyl-1,3- diphenyl-propane-1,3-dione using standard Sharpless asymmetric dihydroxy-lation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form inter-molecular face-to-face π-π contacts, with an inter-planar angle of 15.5 (2)° and a centroid-centroid distance of 4.73 (1) Å. One phenyl ring also forms a C - H⋯π contact to an adjacent imidazole ring, with an H⋯centroid distance of 3.18 Å.
Originalsprog | Engelsk |
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Tidsskrift | Acta Crystallographica. Section E: Structure Reports Online |
Vol/bind | 64 |
Udgave nummer | 3 |
Sider (fra-til) | 619 |
ISSN | 1600-5368 |
DOI | |
Status | Udgivet - 1 mar. 2008 |
Eksternt udgivet | Ja |
ID: 49635401